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Electroplating and wet etching

ELECTROPLATING

The electroplating area deals with 2 technologies:  wet anisotropic etching and electroplating of metals. 


Wet anisotropic etching

The wet anisotropic etching is used for silicon micromachining: the etch thickness varying from some microns to several hundred microns.
The alkaline solutions attack silicon preferentially in the <100> plane, producing a characteristic anisotropic V-etch, with sidewalls that form a 54.7° angle with the surface (35.3° from the normal).
 The KOH etch requires a “hard mask” of silicon dioxide or silicon nitride (nitride is preferred since oxide is slowly etched by KOH).

Electroplating of metals
 

In the electroplating process the substrate is placed in a liquid solution (electrolyte). When an electrical potential is applied between a conducting area on the substrate and a counter electrode (usually platinum) in the liquid, a chemical red-ox process takes place resulting in the formation of a layer of material on the substrate and usually some gas generation at the counter electrode. This process is also known as "electroplating" and is typically restricted to electrically conductive materials. We can plate in the entire wafer or in resist molds from several microns to several hundred microns.



Equipments :

KOH etching (free access)

TMAH etching (free access)



Laboratory reactor for Au plating

Laboratory reactor for Cu plating

Laboratory reactor for Co, Fe, Ni plating

Laboratory reactor for Pb plating


Industrial reactor for Au plating
Industrial reactor for Cu plating

Industrial reactor for FE, Ni, Co plating


Polarography, CVS, Titration for control of plating solutions




sTAFF :

Monique DILHAN (Research Engineer- Area responsible)

David BOURRIER (Engineer Assistant)




Know-how :
  • Anisotropic wet etching :

    KOH etching:
    The etching speed depends on KOH concentration (from 20 to 50 % weight) and temperature (from 50 à 90°) and varies from 0.5 to 2.5 µm /min.

    TMAH etching:

    The etching speed depends on TMAH concentration (from 20 to 50 % weight) and temperature (from 50 à 90°) and varies from 0.2 to 1 µm /min.

    This chemistry doesn’t etch the silicon dioxide, so silicon dioxide can be used as mask









    Realisation of a hole by KOH

     


    Influence of IPA on the etching










    TMAH 20% - 2 min

    TMAH 20% + 17 % IPA - 2 min



  • Electro plating of metals

    Gold plating : Gold electroplating with  continuous current on full wafer or on photoresist moulds for thickness until dozen microns.

    RF-MEMS



    Copper Plating :Copper electroplating with  continuous or pulsed current on full wafer or on photoresist moulds for thickness until hundred microns

    Micro convertiseurs d'énergie


    Co-Ni-Fe plating : NiCoFe electroplating with  continuous current on full wafer or on photoresist moulds for thickness until several dozen microns.

    Micro –Transformers for power components


    Lead plating :
    Lead electroplating with  continuous current on full wafer or on photoresist moulds for thickness until several dozen microns.


    Gold electroless
    in order to protect copper






Imprimer

 
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